Newly-promoted Stuttgart inflicted Mainz's second loss in as many games, as goals from Silas Wamangituka, Daniel Didavi, Mateo Klimowicz and Sasa Kalajdzic secured a 4-1 victory.
Before moving to the NBA, Bender played one season for Maccabi, helping the club to win the Israeli State Cup.
Cedric Bakambu finished second with a stunning strike in the 27th minute after a goal was disallowed for offside in the opening time.
The 64-year-old, who began his managerial career as a teenager in 1975, had previous spells as Botafogo boss in 1986, 1995, 1998 and 2001.
Dortmund continued on the front foot and controlled possession but Augsburg's well-positioned defense defused most attacks in the midfield.
Comments of team leaders indicate growing unrest in a squad that seems to fear their ambitions could be disappointed when trying to repeat some of last season's success after winning the treble.
World champion Xu Jiayu from Zhejiang clinched his second gold in the men's 100m backstroke in 52.60 seconds, after his 200m backstroke victory on Sunday.
Curcurella doubled Getafe's lead with a powerful shot into the corner of the net in the 38th minute and Angel rounded off the scoring with his second of the night after Betis lost possession in midfield.
In the other game in the Chengdu division, after a goalless first half, Taizhou Yuanda broke the deadlock in the 54th minute to claim a 1-0 victory against Beijing Renhe, and Beijing BSU defeated Suzhou Dongwu 3-2.
Messi was the center of attention at the start of the game after his attempt to leave the club over the summer and Friday's criticism of the decision to sell Luis Suarez to Atletico Madrid, but Fati was the hero of the game, scoring in the 15th and 19th minute and then winning a penalty to allow Messi to add a third in a thrilling first half performance.
"[I'm] struggling to walk so that's a tell-tale sign that I should try to recover," she added.